N , N′ ‐Ethylene‐Bridged Bis‐2‐Aryl‐Pyrrolinium Cations to E ‐Diaminoalkenes: Non‐Identical Stepwise Reversible Double‐Redox Coupled Bond Activation Reactions
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چکیده
منابع مشابه
Catalytic Diamination of Olefins via N–N Bond Activation
CONSPECTUS: Vicinal diamines are important structural motifs present in various biologically and chemically significant molecules. Direct diamination of olefins provides an effective approach to this class of compounds. Unlike well-established oxidation processes such as epoxidation, dihydroxylation, and aminohydroxylation, direct diamination of olefins had remained a long-standing challenge an...
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The optical absorption spectra of the delocalized intervalence radical cations of seven o,o'-linked benzidine derivatives that have the nitrogens protected as 9-(9-aza-bicyclo[3.3.1]nonan-3-one) derivatives are discussed and compared with that of the p-phenylene radical cation. The linking units are CH2, CH2CH2, NMe, S, SO2, and C=O, and we also studied H,H (the unlinked benzidine). The lowest-...
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Reduction of N2 to ammonia in nature and in electrocatalysis takes place through 1-proton/1-electron steps, motivating efforts to experimentally study the steps during proton/electron transfer to well-characterized N2-derived species with bridging nitrides. We report here the protonation and reduction reactions of an N2-derived iron bis(nitride) complex (Rodriguez et al., Science, 2011, 334, 78...
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In this paper, we study an (n-k+1)-out-of-n system by adopting their components to be statistically independent though nonidentically distributed. By assuming that at least m components at a fixed time have failed while the system is still working, we obtain the mixture representation of survival function for a quantity called the conditional inactivity time of failed components in the system. ...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2020
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.202000255